Electrochemical impedance detection of Hg2+, Ni2+ and Eu3+ ions by a new azo-calix[4]arene membrane
Identifieur interne : 000105 ( France/Analysis ); précédent : 000104; suivant : 000106Electrochemical impedance detection of Hg2+, Ni2+ and Eu3+ ions by a new azo-calix[4]arene membrane
Auteurs : R. Ebdelli [Tunisie, France] ; A. Rouis [Tunisie] ; R. Mlika [Tunisie] ; I. Bonnamour [France] ; N. Jaffrezic-Renault [France] ; H. Ben Ouada [Tunisie] ; J. Davenas [France]Source :
- Journal of electroanalytical chemistry : (1992) [ 1572-6657 ] ; 2011.
Descripteurs français
- Pascal (Inist)
- Composé azoïque, Matériau modifié, Mercure II Composé, Nickel II Composé, Préparation, Calixarène, Microscopie électronique balayage, Angle contact, Chromophore, Or, Electrode, Schéma équivalent, Impédancemétrie, Europium III Complexe, Analyse chimique, Analyse quantitative, Métal lourd, Composé inclusion, Cyclophane, Spectrométrie impédance électrochimique, Macrocycle, Structure surface, Morphologie, Propriété surface, Détecteur électrochimique.
- Wicri :
- topic : Or, Analyse quantitative, Métal lourd.
English descriptors
- KwdEn :
- Azo compound, Calixarene, Chemical analysis, Chromophore, Contact angle, Cyclophane, Electrochemical detector, Electrochemical impedance spectroscopy, Electrodes, Equivalent circuit, Europium III Complexes, Gold, Heavy metal, Impedancemetry, Inclusion compound, Macrocycle, Mercury II Compounds, Modified material, Morphology, Nickel II Compounds, Preparation, Quantitative analysis, Scanning electron microscopy, Surface properties, Surface structure.
Abstract
Due to their recognition properties and efficiency for the detection of toxic metals, calixarenes have already found applications in the design of chemical sensors based on using an electrochemical transduction. In this study, a new chromogenic azo-calix[4]arene derivative was deposited on gold electrode by spin coating to develop a new electrochemical sensor. Adhesion and morphological properties of the membrane have been firstly developed using contact angle measurements and scanning electronic microscopy (SEM) respectively. Electrochemical impedance spectroscopy (EIS) is used to study the response of the calixarenes membrane in contact with aqueous solutions of various metallic cations. The impedance behavior of the structures has been modeled by an equivalent circuit using the Z-View software. This technique has shown a selective response of this membrane towards Hg2+, Ni2+ and Eu3+. The differences in selectivity are found to be represented by variations in the resistance of the membrane (Rm) and in the charge transfer resistance (Rct) of the interface. Variation of CPE1 and CPE2 have been also investigated which were correlated to the porosity of the film and the exchange of the charge between the substrate and the electrolyte respectively.
Affiliations:
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Pascal:12-0283734Le document en format XML
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ions by a new azo-calix[4]arene membrane</title>
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<series><title level="j" type="main">Journal of electroanalytical chemistry : (1992)</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Azo compound</term>
<term>Calixarene</term>
<term>Chemical analysis</term>
<term>Chromophore</term>
<term>Contact angle</term>
<term>Cyclophane</term>
<term>Electrochemical detector</term>
<term>Electrochemical impedance spectroscopy</term>
<term>Electrodes</term>
<term>Equivalent circuit</term>
<term>Europium III Complexes</term>
<term>Gold</term>
<term>Heavy metal</term>
<term>Impedancemetry</term>
<term>Inclusion compound</term>
<term>Macrocycle</term>
<term>Mercury II Compounds</term>
<term>Modified material</term>
<term>Morphology</term>
<term>Nickel II Compounds</term>
<term>Preparation</term>
<term>Quantitative analysis</term>
<term>Scanning electron microscopy</term>
<term>Surface properties</term>
<term>Surface structure</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Composé azoïque</term>
<term>Matériau modifié</term>
<term>Mercure II Composé</term>
<term>Nickel II Composé</term>
<term>Préparation</term>
<term>Calixarène</term>
<term>Microscopie électronique balayage</term>
<term>Angle contact</term>
<term>Chromophore</term>
<term>Or</term>
<term>Electrode</term>
<term>Schéma équivalent</term>
<term>Impédancemétrie</term>
<term>Europium III Complexe</term>
<term>Analyse chimique</term>
<term>Analyse quantitative</term>
<term>Métal lourd</term>
<term>Composé inclusion</term>
<term>Cyclophane</term>
<term>Spectrométrie impédance électrochimique</term>
<term>Macrocycle</term>
<term>Structure surface</term>
<term>Morphologie</term>
<term>Propriété surface</term>
<term>Détecteur électrochimique</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Or</term>
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</textClass>
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<front><div type="abstract" xml:lang="en">Due to their recognition properties and efficiency for the detection of toxic metals, calixarenes have already found applications in the design of chemical sensors based on using an electrochemical transduction. In this study, a new chromogenic azo-calix[4]arene derivative was deposited on gold electrode by spin coating to develop a new electrochemical sensor. Adhesion and morphological properties of the membrane have been firstly developed using contact angle measurements and scanning electronic microscopy (SEM) respectively. Electrochemical impedance spectroscopy (EIS) is used to study the response of the calixarenes membrane in contact with aqueous solutions of various metallic cations. The impedance behavior of the structures has been modeled by an equivalent circuit using the Z-View software. This technique has shown a selective response of this membrane towards Hg<sup>2+</sup>
, Ni<sup>2+</sup>
and Eu<sup>3+</sup>
. The differences in selectivity are found to be represented by variations in the resistance of the membrane (R<sub>m</sub>
) and in the charge transfer resistance (R<sub>ct</sub>
) of the interface. Variation of CPE<sub>1</sub>
and CPE<sub>2</sub>
have been also investigated which were correlated to the porosity of the film and the exchange of the charge between the substrate and the electrolyte respectively.</div>
</front>
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<name sortKey="Davenas, J" sort="Davenas, J" uniqKey="Davenas J" first="J." last="Davenas">J. Davenas</name>
<name sortKey="Jaffrezic Renault, N" sort="Jaffrezic Renault, N" uniqKey="Jaffrezic Renault N" first="N." last="Jaffrezic-Renault">N. Jaffrezic-Renault</name>
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